unsure as to why else statement is not working?

G'day!

You did a small mistake in the script, so here is the fixed one:

local clickDetector = workspace.button.ClickDetector

local clicked = false

function onClicked(player)
    if not clicked then 
        clicked = true 
        if player.Character then
            player.Character:MoveTo(Vector3.new(-11, -1.9, -16.45))
        end
    else
        clicked = false
        if player.Character then
            player.Character:MoveTo(Vector3.new(-27.2, 0.5, 15.5))
        end
    end
end

script.Parent.ClickDetector.MouseClick:connect(onClicked)