What does it mean when people say that module scripts cache?

It means a module script will always return the same value.

--In a module script
return math.random(1,9)

--In a script
while true do
	print(require(script.ModuleScript))
	wait(1)
end

And it only prints 1 number, every second, the same number.

--Another example moduleScript
return game.Workspace.Value.Value

--Script
while true do
	print(require(script.ModuleScript))
	--prints the original value repeatedly
	game.Workspace.Value.Value = game.Workspace.Value.Value .. " and antoher one"
	wait(1)
end

So here, the module script doesn't run twice, it only looks up what it returned previously, and gives returns that, even though the value it looks at changes.

Explain it a bit better: A module script runs once, and only once. Adding a print statement to the beginning will show this:

print("Important code bits")
--The above only prints once
return game.Workspace.Value.Value

And if it is required again, it just returns what it did the previous time it was required.

Reasons? The same reasons anything caches, to improve performance. Module scripts shouldn't be used to return values like in the above examples anyway.

As for the same environment thing, a module script would be ran once from the server, and once on each client that requires it.

return game.Players.LocalPlayer

Would return nil if required from a serverScript, and return the local player if required from a LocalScript.