Why won't this scrip work?

This code is definitely poorly designed.

Let's begin by tabbing your code properly

button = script.Parent
while true do 
	wait(1)
	button.Rotation = button.Rotation + 2
	if button.Rotation == 20 then
		button.Rotation = button.Rotation - 2
		if button.Rotation == - 20 then
			button.Rotation = button.Rotation + 2
			wait(.1)
		end
	end
end

Notice that the second if for adding to Rotation is inside the other one. That is almost certainly not what we want.

The wait(.1) similarly doesn't belong, probably.

button = script.Parent
while true do 
	wait(1)
	button.Rotation = button.Rotation + 2
	if button.Rotation == 20 then
		button.Rotation = button.Rotation - 2
	end
	if button.Rotation == - 20 then
		button.Rotation = button.Rotation + 2
	end
end

We can also see that we're adding twice here instead of just once. That doesn't seem right, and it probably isn't, let's drop it.

button = script.Parent
while true do 
	wait(1)
	if button.Rotation == 20 then
		button.Rotation = button.Rotation - 2
	end
	if button.Rotation == - 20 then
		button.Rotation = button.Rotation + 2
	end
end

Now, here's a problem. Usually, Rotation won't be either 20 or -20. It can be something in between. Let's use a variable for the direction instead, and just change direction when we get to the ends:

button = script.Parent
direction = 2
while true do
	wait(1)
	button.Rotation = button.Rotation + direction
	if button.Rotation == 20 then
		direction = -2
		-- Turn around!
	end
	if button.Rotation = -20 then
		direction = 2
		-- Turn around!
	end
end

It would also probably be better to use >= and <= instead of ==, just in case the numbers don't add up to exactly 20 (e.g., if you change the numbers, or things get more complicated)

while true do
	wait(1)
	button.Rotation = button.Rotation + direction
	if button.Rotation >= 20 then
		direction = -2
	end
	if button.Rotation <= -20 then
		direction = 2
	end
end

We could make this a little cleaner and simpler by using button.Rotation's magnitude (absolute value) instead of the separate numbers 20 and -20:

	...
	if math.abs(button.Rotation) >= 20 then
		direction = -button.Rotation / 10
	end
	...

Or, instead of the linear jump back and forth, we could make things smooth by using a sin (sine) function:

button = script.Parent
time = 0
while true do
	time = time + wait(0.2)
	button.Rotation = 20 * math.sin( time )
end